- How do you achieve good adhesion for conformal coatings?
- What is Chemical Bonding for adhesion of conformal coatings?
- What is Mechanical Interlocking for adhesion of conformal coatings?
- What is surface contamination when considering conformal coatings?
- What is the adsorption mechanism for adhesion of conformal coating?
Generally, conformal coatings must exhibit good adhesion in order to be effective. However, there is no single theory that describes the property of adhesion for coatings.
There are several basic mechanisms for coatings that are known to define good adhesion. They are Adsorption, Chemical Bonding, and Mechanical Interlocking:
- Adsorption is where the molecules in the conformal coating wet or flow freely over the substrate and make intimate contact with the substrate. This forms interfacial (electrostatic) bonds with van-der-Waal forces.
- Chemical bonds are formed at the interface between the conformal coating and the substrate.
- The conformal coating film penetrates the roughness on the substrate surface. This results in mechanical interlocking once the coating dries.
All three of mechanisms do not have to occur to form good adhesion. Depending on the specific conformal coating system, substrate, and application method, different mechanisms could work. However, good wetting or adsorption is normally required.
Certain coatings are formulated with binders that have a functional group that can chemically bond to a compatible substrate. In these applications the formation of covalent chemical bonds occurs across the interface. These strong and durable bonds are generally the result of close contact or adsorption of the adhesive on the surface followed by a chemical reaction.
Conformal coating systems containing reactive functional groups, such as hydroxyl or carbonyl, tend to adhere more tenaciously to substrates containing similar groups. Hydroxyl bonding is one of the reasons why epoxy and polyurethane base polymers are often used in in many formulations.
Perhaps the most widely employed example of chemical bonding in the conformal coating industry is with adhesion promoters or coupling agents. These multifunctional chemicals provide a “molecular bridge” between the substrate and the molecules in the conformal coating film. One end of the adhesion promoter molecule has functionality that will react with the conformal coating and the other end has a functionality that will react with the substrate. A strong and durable bond forms as the coating cures.
The use of an adhesion promoter is extensive in Parylene coating since Parylene is extremely poor at adhering to the surface. Organosilane is an example of a widely used adhesion promoter specifically in Parylene.
The surface of a solid material is never truly smooth. It normally consists of a maze of peaks and valleys. These are pores, holes, crevices and micro-voids on the substrate.
According to the mechanical theory of adhesion, in order to function properly a conformal coating must penetrate the irregularities on the surface, displacing the trapped air at the interface, and lock-on mechanically to the substrate.
One way that surface roughness aids in adhesion is by increasing the total contact area between the conformal coating and the surface. If interfacial or intermolecular attraction is the basis for adhesion, increasing the actual area of contact will increase the total energy of surface interaction by a proportional amount.
Another benefit of mechanical interlocking is that a rough surface will provide a crack propagation barrier and stop the coating lifting from the substrate.
For a smooth interface, little energy dissipation may be required to separate the coating from the surface and a clean separation is possible. However, if there is surface roughness, then the interface between the adhering materials will act as “path breaks” between the separating coating and substrate. These excursions dissipate energy and increase the resulting strength of the bond.
Thus, there are many cases where the forces of adhesion and mechanical interlocking are working together at the substrate interface.
According to Weldon (2009) surface preparation is a critical factor in obtaining good adhesion.
Soils and other contaminants inhibit adhesion through though both chemical and physical pathways. This is done by reducing the influence of intermolecular forces between the surface and the applied material, or by blocking sites that provide an opportunity for physical anchoring.
Also Schuman and Thames (2005) states that a variety of important coating properties such as hardness, scratch resistance, chip resistance and gloss are affected by the underlying surface’s hardness, smoothness and adhesion to the coating.
So, surface contamination can be critical when considering conformal coating and the process.
The theory of Adsorption states that good adhesion occurs from molecular contact between two materials and the surface forces that are developed. A bond develops from the adsorption of conformal coating molecules on the substrate and the resulting attractive forces, usually designated as secondary (van der Waals) forces.
For these forces to develop, the respective surfaces must not be separated by more than five angstroms in distance. Therefore, the conformal coating film must make intimate, molecular contact with the substrate surface.
The process of establishing continuous contact between a conformal coating and the substrate surface is known as wetting.
Good wetting occurs when the conformal coating flows into the valleys and crevices on the substrate surface. Poor wetting results when the conformal coating bridges over the surface irregularities.
In order for good wetting to occur, the substrate must have a higher surface energy than the conformal coating film. Many materials have a higher surface energy than the conformal coatings being applied. Therefore, wetting is simple. However, if the substrate is contaminated with a lower surface energy material then wetting may be prevented.
Also, if the substrate is contaminated with particulates then a weak boundary layer could be formed that can easily fail cohesively and therefore weaken the conformal coating system.